Monday, 21 May 2012

Classes of Organic Compounds: Part Two

Amines

  • Functional Group: 
    • -NH2 
  • General Formula:  
    • R-NH2 
  • Naming:  
    • Name the parent chain (methane, ethane, propane...)  
    • Substitute the "-e" ending with the suffix "-amine" (methanamine, ethanamine, propanamine...) 
  • Examples:  
    • C6H15--> hexylamine 
    • CH3CH2NH2 --> ethylamine 
    • C4H11N --> butylamine 
    • CH3CH2CH2CH2CH2CH2CH2CH2NH2  --> octylamine

structure of nonylamine
    • Above diagram --> nonylamine



Amides 










  • Naming:  
    • Name the parent chain (methane, ethane, propane...)  
    • Substitute the "-e" ending with the suffix "-amide" (methanamide, ethanamide, propanamide...) 
  • Examples:  
    • CH3NO --> methanamide 
    • CH3CH2CONH2 --> propanamide
    • C10H21NO --> decanamide 
    • CH3CH2CH2CH2CH2CH2CH2CONH2 --> octanamide

Structure of heptanamide
    • Above diagram --> heptanamide  



Nitro

  • Functional Group: 
    • CN 
  • General Formula:  
    • R-CN
  • Naming:  
    • Name the parent chain (methane, ethane, propane...)  
    • Add to the "-e" ending,  the suffix "-nitrile" (methanenitrile, ethanenitrile, propanenitrile...) 
  • Examples:  
    • CH3CH2CH2CN --> butanenitrile 
    • CH3CH2CH2CH2CH2CH2CN  --> heptanenitrile

structure of octanenitrile
    • Above diagram --> octanenitrile  

Esters







  • Naming:  
    • Name the parent chain (methane, ethane, propane...)  
    • Substitute the "-e" ending with the suffix "-oate" (methanoate, ethanoate, propanoate...) 
    • Name the side chain that appears past the oxygen bond (methyl, ethyl, propyl...
    • Place the side chain name in front of the modified parent chain name (methyl methanoate)
  • Examples:  
    • C2H4O2 --> methyl methanoate 
    • C5H10O2 --> methyl butanoate 
    • C9H18O2 --> propyl hexanoate 
    • C6H12O2--> ethyl butanoate

molecular structure of methyl hexanoate
    • Above diagram --> methyl hexanoate  

molecular structure of propyl propanoate


    • Above diagram --> propyl propanoate 

Below is a video lesson further expanding what we have covered in the past several lessons of the many classes of organic compounds: 
-Simon Sierra

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