Monday, 24 October 2011

Bohr Diagrams

Bohr Model

- Atoms are electrically neutral
- Two different models can be used to describe electron configuration
  1. Energy level model
  2. Bohr model
- Electrons occupy shells which are divided into orbitals
  1.  2e− in the first orbital
  2.  8e− in the second orbital
  3.  8e− in the third orbital  

Energy level model for Argon.



Protons = 18
Neutrons = 22
Electrons = 18













Bohr diagram for Oxygen.


Protons = 8
Neutrons = 8
Electrons = 16






~Ben Suratos

Tuesday, 11 October 2011

Bohr's Model

What is Bohr's Model? 
Niels Bohr concluded that Rutherford's model was inherently unstable as the protons and electrons Rutherford had proposed should, in all likelihood attract each other. With this in my mind, Bohr suggested his own theory. This entailed that:

  • Electron's exist in orbitals 
  • When they absorb energy, they move to a higher orbital
  • When they release energy (as a photon of light), they move to a lower orbital 
 


What Did Bohr Base His Model On? 
Knowing that white light can be separated into colours with a diffraction prism of sorts, Bohr could postulate that each element emitted an unique set of colours or line. Each atom had a specific spectra of light and this uniqueness of the elements was reflected by how electrons occupied their orbital shells. 
Visually these differences can be shown with a Bohr Model (as shown above) or an emission spectrum. 

Hydrogen can appear as follows: 



For a very in-depth look at Bohr's Model and Spectra feel free to click here.

-Simon Sierra

Wednesday, 5 October 2011

Atomic Theories

Theories on the structure and behaviour of atoms have been evolving for more than two millennia. The following are key theories introduced by important individuals who have shaped the ideas of physical world to what they are today.

Democritus Postulates Atoms as "Indivisible Particles"
Around 400 BC, a Greek philosopher and early scientist by the name of Democritus theorized that all matter is made up of atoms. He described atoms as the smallest particles of an element that retain the chemical identity of that element. While this is only a conceptual view, it was one of the first to challenge the ancient perspective of all matter being composed of Earth, Wind, Fire and Water. It may have lacked certain scientific evidence but it acted as a base theory for following generations in science to build upon.


Antoine Lavoisier Pioneers the "Law of Conservation of Mass"
As the name of his theory suggests, the French nobleman suggested during the eighteenth century that mass is conserved in a chemical reaction. He explained that chemical reaction neither produce mass or destroy mass. Lavoisier's theory was later included in that of John Dalton's as described later on. 

Joseph Proust Form's "Proust's Law"
Another Frenchman, it was in the late eighteenth century that Proust created a Law of Constant Composition also known as the eponymous "Proust's Law." He theorized that a given compound always contains the same elements in the same proportion by mass. Essentially this law of definite proportions claims that water will always include 89% oxygen and 11% hydrogen regardless of the amount of molecules found in any sample. 

John Dalton's "Atomic Theory of Matter"
This monumental hypothesis of John Dalton borrowed from earlier theories to develop what was the most definite and conclusive postulation of the time. It was based in the following: 
  • Each element is composed of extremely small particles called atoms. 
  • All atoms of a given element are identical, but they differ from those of any other element. 
  • Atoms are neither created or destroyed in any chemical reaction (Lavoisier's Law of Conservation of Mass) 
  • A given compound always has the same relative numbers and kinds of atoms (Proust's Law of Constant Composition)  

J.J Thomson's "Raisin Bun" Model
In 1897, Thomson took John Dalton's ideas to a new level. He added an extra component in electrically charged particles. He implicated this into a "Raisin Bun" similar to atoms being solid spheres made-up of a solid positive mass (or core) with tiny negative particles embedded in the positive core. These positive particles became known as protons while the negative charged ones are called electrons.  

Ernest Rutherford's Planetary Model
Studying under J.J. Thomson, Rutherford became very familiar with the Raisin Bun model and used a famous experiment to make detail examinations on the composition of a atom. It was his "Gold-Leaf Experiment" which proved that the nucleus is a positively charged for core of the atom which holds protons and neutrons. Neutrons have no charge. Existing outside of this nucleus was a great deal of empty space housing spinning rings of electrons. 

Each of these theories have contributed to how we see the world today. They took us from conceptual knowledge of the physical to a tangible and scientific one. To learn more, and see a chart organizing the above information, feel free to click here.  

-Simon Sierra

Tuesday, 4 October 2011

Density and Graphing




What is Density
Density is Mass divided by volume. It is a measurement of the amount of matter in a given volume of something. Density is a very important property which can be used to identify a substance. Density is usually expressed in Kg/L, Kg/m3or g/cm3

Graphing
All graphs must contain 5 important things
1.) Labelled axis
2.) Appropriate scale
3.) Title
4.) Data points
5.) Line of best fit

Three things can be done when working with graphs
1.) Be able to read the graph
2.) Be able to find the slope
3.) Be able to find the area under the graph

-George Spencer

Sunday, 2 October 2011

Dimensional Analysis

Dimensional analysis is the technique of converting between units.

There are only four steps for this technique.
  1. Identify what units you want to end up with
  2. Find the conversion factors
  3. Place units in the appropriate places
  4. Cancel units
Ex:

How many seconds are in 1.4 hours?
1.4h x 3600s/1h = 5040s

Ex.

What is 50km/h in m/s?
50km/h x 1h/3600s x 1000m/1km = 13.88888889
                                                     =14m/s

-Benedict Suratos

Significant Digits

When are digits significant?
Non-zero digits are always significant. Thus, 22 has two significant digits, and 22.3 has three significant digits.




With zeroes, the situation is more complicated:
  1. Zeroes placed before other digits are not significant; 0.046 has two significant digits.
  2. Zeroes placed between other digits are always significant; 4009 kg has four significant digits.
  3. Zeroes placed after other digits but behind a decimal point are significant; 7.90 has three significant digits.
  4. Zeroes at the end of a number are significant only if they are behind a decimal point as in (c). Otherwise, it is impossible to tell if they are significant. For example, in the number 8200, it is not clear if the zeroes are significant or not. The number of significant digits in 8200 is at least two, but could be three or four. To avoid uncertainty, use scientific notation to place significant zeroes behind a decimal point.      
Significant Digits in Multiplication, Division
In multiplication and division, the measurement with the smallest number of significant digits determines how many digits are allowed in the final answers.

Significant Digits in Addition, Subtraction
In addition and subtraction, the number of significant digits allowed depends on the number with the largest uncertainty. 


-George Spencer

Wednesday, 28 September 2011

Units of Measurement and Uncertainty in Measurement

Prefixes Used with SI Units

We can put a prefix in front of the unit and change the power of it.

    - tera: 10^12                                    - femto: 10^-15
    - giga: 10^9                                      - pico: 10^-12
    - mega: 10^6                                   - nano: 10^-9

    - kilo: 10^3                                     - micro:10^-6

    - hecto: 10^2                                   - milli: 10^-3

    - deca : 10^1                                   - centi: 10^-2



    SI Prefixes

    the SI System uses many prefixes to represent very large or very small numbers
    Experimental Accuracy 
    In general the maximum accuracy of any measurement is one half of the smallest division of the measuring device.A ruler with measurements of the millimeters has a maximum accuracy of positive or negative 0.5mm
    Expressing Error 
    Error is a fundamental part of science
    There are usually 3 reasons for error: 
                         > physical errors in the measuring device 
                         > "sloppy" measurements
                         > changing ambient conditions 

    Calculating Errors  
    Two different possibilities: Absolute Error, Percentage Error 
    Absolute Error
      
    Measured value minus accepted value  
    Absolute Error = Measured - Accepted 
    Percent Error  
    Most common 
    Percent error = Absolute error/Accepted value 


    -Benedict Suratos